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Application · Plastic Modification

MAH Grafted PP/PE: Continuous Melt Grafting

Maleic anhydride grafting is a reaction with a narrow window: below 190 °C the initiator never breaks down, above 230 °C the graft level falls as fast as it rose. A reference mah grafted pp page from Kerke.

MAH Grafted PP PE — workshop photo 1, Kerke workshop, NanjingMAH Grafted PP PE — workshop photo 1, Kerke workshop, Nanjing
MAH Grafted PP PE — workshop photo 2, Kerke workshop, NanjingMAH Grafted PP PE — workshop photo 2, Kerke workshop, Nanjing
MAH Grafted PP PE — workshop photo 3, Kerke workshop, NanjingMAH Grafted PP PE — workshop photo 3, Kerke workshop, Nanjing
MAH Grafted PP PE — workshop photo 4, Kerke workshop, NanjingMAH Grafted PP PE — workshop photo 4, Kerke workshop, Nanjing
MAH Grafted PP PE — workshop photo 5, Kerke workshop, NanjingMAH Grafted PP PE — workshop photo 5, Kerke workshop, Nanjing
MAH Grafted PP PE — workshop photo 6, Kerke workshop, NanjingMAH Grafted PP PE — workshop photo 6, Kerke workshop, Nanjing
Running video — MAH Grafted PP PE, Kerke workshop
Running video — MAH Grafted PP PE, Kerke workshop

Quick answer

MAH grafting (MAH-g-PP, MAH-g-PE, compatibilizers) runs as continuous reactive extrusion at 190–220 °C with L/D 48–52, multi-stage vacuum devolatilization and a strand or underwater pelletizer. Output 100–800 kg/h. Residual maleic anhydride and peroxide dosing accuracy decide product quality.

0.8–1.2%graft level
190–210 °CPP reaction zone
<0.3%residual MAH

Workshop photos and a running video — shot on our own lines, not stock images.

What sets the limit

Resin, MAH and initiator are metered separately, melted and reacted in dedicated kneading blocks, then devolatilized twice to strip unreacted monomer before pelletizing.

Table 1. Key parameters for mah grafted material pelletizing line. Reference values — confirm on a material trial.
ParameterValue / range
Reaction temperature190–220 °C
L/D48–52
Devolatilization2-stage vacuum, < -0.09 MPa
Output (reference)100–800 kg/h
PelletizingStrand (preferred) or underwater
ModelKTE-50B, KTE-65B

Output figures are measured on the reference material stated above. Filler grade, bulk density and moisture move output by ±15% — that is why every quotation we issue is tied to a trial report.

Process flow, step by step

  1. FeedingLoss-in-weight dosing of polymer and filler; side feeder or liquid injection where the formulation needs it.
  2. Melting and dispersingScrew geometry with 45°/90° kneading blocks; barrel profile set by the polymer.
  3. DevolatilizationVacuum vent at −0.06 to −0.09 MPa removes moisture and volatiles before the die.
  4. Pressure build-upThrottle or discharge section stabilises die pressure; a melt pump where gauge control matters.
  5. Pelletizing and packingStrand (preferred) or underwater; then centrifugal dryer, vibrating screen and bagging.

Equipment configuration

Table 2. What the line is made of, and why each part is specified that way.
StageEquipmentWhy this choice
Main machineCo-Rotating Twin Screw ExtruderArchitecture follows the filling level and the mixing duty, not the required tonnage.
Screw geometryBuilding-block elements, W6Mo5Cr4V2, bimetallic linerWear package for abrasive filler; mixing blocks only where dispersion demands them.
FeedingLoss-in-weight feeder, side feeder where neededRecipe accuracy: ±0.5% short term on the weighed component.
PelletizingPelletizing systemChosen by polymer and filler ceiling — water contact is the deciding column.
DownstreamCentrifugal dryer, vibrating screen, baggingFines below 2% and moisture below the specification of your downstream process.

Output by model

Table 3. Co-rotating twin screw KTE — reference output. Full range on the machine page.
ModelDia. (mm)Speed (rpm)Motor (kW)Torque (N·m)Output (kg/h)
KTE-50B50.5500–60055–752×52580–200
KTE-50D50.5300–80075–902×860100–300
KTE-52B51.4500–60055–752×72080–200
KTE-52D51.4500–60075–1102×1050100–400
KTE-65B62.4500–60090–1102×860200–450
KTE-65D62.4300–800132–1602×1530350–600
KTE-75B71500–600132–1602×1530300–800
KTE-75D71300–800200–3152×2100500–1000
KTE-85B85500–600220–3152×2100550–1000
KTE-95B93500–600250–3152×3000800–1500
KTE-95D93500–800315–5002×48001000–2000
KTE-135B135500–600315–5002×48001500–3000
KTE-135D135500–800500–10002×78001500–4000

Three mistakes that cost the most

1. Insufficient devolatilization

Insufficient devolatilization — residual MAH smells and fails the customer's VOC spec.

2. Peroxide fed by a volumetric pump: dosing drift changes grafting degree batch to batch.

Peroxide fed by a volumetric pump: dosing drift changes grafting degree batch to batch.

3. Residence time left uncontrolled

Residence time left uncontrolled — grafting peaks in a narrow window, and over-long mixing drops the graft degree while gelling the melt; reactive duty wants 52–60D with two vents.

FAQ

What grafting degree is achievable?

0.8–1.2% for MAH-g-PP is routine. Above 1.5% the melt viscosity and yellowing become hard to control.

Do I need explosion-proof design?

For MAH powder handling, yes — the feeding area requires dust-rated electrical equipment depending on local regulation.

What output can you guarantee for this application?

The reference band is 100–800 kg/h, measured on the stated material. We quote a guaranteed figure only after a trial on your own material, because filler grade, bulk density and moisture move output by ±15%.

Can we run our material before ordering?

Yes — send 25–50 kg. We return pellets, a running video and a report with temperatures, screw speed, feeder settings and output per hour. The trial is free; you cover the freight.

What is the delivery time?

30–45 working days for standard configurations, 45–70 for custom screw geometry and ODM work. Voltage and frequency are built for the destination country.

Where these numbers come from

Parameters are taken from the Kerke product parameter table and the product master data sheet, and cross-checked against commissioning records for lines in the same application. Formulations and temperature windows are typical industry values, not a recommendation for your specific compound — every figure marked reference must be confirmed on a material trial before it becomes a contractual number.

Reviewed by the Kerke process team, Nanjing. Page updated 6 November 2026.

Tell us your material — we will tell you the line

Send 25–50 kg and we run it on our lab extruder: pellets, running video and a capacity report back in 3–7 days.

MAH grafted pp — the short version

Note on mah grafted pp: the numbers above are reference ranges from Kerke's own trial runs, not catalogue promises. Screw geometry, wear package and pelletizing method are set on the trial bench first, so the output you compare is the output you get. If your grade is not in the tables, send it — the closest configuration is usually a change of screw set, not a different machine.

Related on this site: Machine range: KTE-50B to 135D · Pelletizing methods compared · quotation and free trial · Wikipedia: Masterbatch