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Application · Plastic Modification

TPU Reactive Extrusion: Continuous Polymerization

TPU is polymerized inside the extruder, which makes it the one product where moisture is not a quality issue but a stoichiometry error: one gram of water consumes isocyanate and caps molecular weight. A reference tpu reactive extrusion page from Kerke.

TPU Reactive Extrusion — workshop photo 1, Kerke workshop, NanjingTPU Reactive Extrusion — workshop photo 1, Kerke workshop, Nanjing
TPU Reactive Extrusion — workshop photo 2, Kerke workshop, NanjingTPU Reactive Extrusion — workshop photo 2, Kerke workshop, Nanjing
TPU Reactive Extrusion — workshop photo 3, Kerke workshop, NanjingTPU Reactive Extrusion — workshop photo 3, Kerke workshop, Nanjing
TPU Reactive Extrusion — workshop photo 4, Kerke workshop, NanjingTPU Reactive Extrusion — workshop photo 4, Kerke workshop, Nanjing
TPU Reactive Extrusion — workshop photo 5, Kerke workshop, NanjingTPU Reactive Extrusion — workshop photo 5, Kerke workshop, Nanjing
TPU Reactive Extrusion — workshop photo 6, Kerke workshop, NanjingTPU Reactive Extrusion — workshop photo 6, Kerke workshop, Nanjing
Running video — TPU Reactive Extrusion, Kerke workshop
Running video — TPU Reactive Extrusion, Kerke workshop

Quick answer

TPU can be produced by continuous reactive extrusion instead of batch casting: diisocyanate and polyol are metered into a twin screw with L/D 52–60, reacted under controlled shear, devolatilized and underwater pelletized. Output 200–1,000 kg/h with much tighter batch-to-batch variation than a batch reactor.

48–60screw L/D
120→200 °Csegmented profile
1.0–1.05NCO/OH ratio

Workshop photos and a running video — shot on our own lines, not stock images.

What sets the limit

Polyol and isocyanate are degassed, metered and injected into the first mixing zone; chain extender follows; the melt reacts along the barrel, is devolatilized and pelletized underwater. Residence time distribution is what determines hardness consistency.

Table 1. Key parameters for tpu reactive extrusion line. Reference values — confirm on a material trial.
ParameterValue / range
ProcessContinuous reactive extrusion (one-shot or prepolymer)
L/D52–60
Temperature180–220 °C, staged
Metering accuracy±0.5% gravimetric, heated lines
Output (reference)200–1,000 kg/h
ModelKTE-65B, KTE-75B, KTE-95B

Output figures are measured on the reference material stated above. Filler grade, bulk density and moisture move output by ±15% — that is why every quotation we issue is tied to a trial report.

Process flow, step by step

  1. FeedingLoss-in-weight dosing of polymer and filler; side feeder or liquid injection where the formulation needs it.
  2. Melting and dispersingScrew geometry with 45°/90° kneading blocks; barrel profile 180–220 °C, staged.
  3. DevolatilizationVacuum vent at −0.06 to −0.09 MPa removes moisture and volatiles before the die.
  4. Pressure build-upThrottle or discharge section stabilises die pressure; a melt pump where gauge control matters.
  5. Pelletizing and packingdie-face or strand pelletizing, see the pelletizing page; then centrifugal dryer, vibrating screen and bagging.

Equipment configuration

Table 2. What the line is made of, and why each part is specified that way.
StageEquipmentWhy this choice
Main machineCo-Rotating Twin Screw ExtruderArchitecture follows the filling level and the mixing duty, not the required tonnage.
Screw geometryBuilding-block elements, W6Mo5Cr4V2, bimetallic linerWear package for abrasive filler; mixing blocks only where dispersion demands them.
FeedingLoss-in-weight feeder, side feeder where neededRecipe accuracy: ±0.5% short term on the weighed component.
PelletizingPelletizing systemChosen by polymer and filler ceiling — water contact is the deciding column.
DownstreamCentrifugal dryer, vibrating screen, baggingFines below 2% and moisture below the specification of your downstream process.

Output by model

Table 3. Co-rotating twin screw KTE — reference output. Full range on the machine page.
ModelDia. (mm)Speed (rpm)Motor (kW)Torque (N·m)Output (kg/h)
KTE-50B50.5500–60055–752×52580–200
KTE-50D50.5300–80075–902×860100–300
KTE-52B51.4500–60055–752×72080–200
KTE-52D51.4500–60075–1102×1050100–400
KTE-65B62.4500–60090–1102×860200–450
KTE-65D62.4300–800132–1602×1530350–600
KTE-75B71500–600132–1602×1530300–800
KTE-75D71300–800200–3152×2100500–1000
KTE-85B85500–600220–3152×2100550–1000
KTE-95B93500–600250–3152×3000800–1500
KTE-95D93500–800315–5002×48001000–2000
KTE-135B135500–600315–5002×48001500–3000
KTE-135D135500–800500–10002×78001500–4000

Three mistakes that cost the most

1. Moisture in polyol

Moisture in polyol — a 0.05% water content ruins the stoichiometry and the hardness.

2. Insufficient mixing length: unreacted isocyanate shows up as sticky pellets and die drool.

Insufficient mixing length: unreacted isocyanate shows up as sticky pellets and die drool.

3. Underwater chamber temperature drifting

Underwater chamber temperature drifting — the water circuit must hold ±2 °C, or TPU pellets solidify unevenly, double up and block the screen.

FAQ

Is continuous TPU equivalent to batch TPU?

Mechanically yes when the stoichiometry and residence time are controlled; the advantage is consistency, not a different chemistry.

What output is realistic for 85A?

400–600 kg/h on a KTE-75B; harder grades run slower because the melt viscosity rises.

What output can you guarantee for this application?

The reference band is 200–1,000 kg/h, measured on the stated material. We quote a guaranteed figure only after a trial on your own material, because filler grade, bulk density and moisture move output by ±15%.

Can we run our material before ordering?

Yes — send 25–50 kg. We return pellets, a running video and a report with temperatures, screw speed, feeder settings and output per hour. The trial is free; you cover the freight.

What is the delivery time?

30–45 working days for standard configurations, 45–70 for custom screw geometry and ODM work. Voltage and frequency are built for the destination country.

Where these numbers come from

Parameters are taken from the Kerke product parameter table and the product master data sheet, and cross-checked against commissioning records for lines in the same application. Formulations and temperature windows are typical industry values, not a recommendation for your specific compound — every figure marked reference must be confirmed on a material trial before it becomes a contractual number.

Reviewed by the Kerke process team, Nanjing. Page updated 6 November 2026.

Tell us your material — we will tell you the line

Send 25–50 kg and we run it on our lab extruder: pellets, running video and a capacity report back in 3–7 days.

TPU reactive extrusion — the short version

Note on tpu reactive extrusion: the numbers above are reference ranges from Kerke's own trial runs, not catalogue promises. Screw geometry, wear package and pelletizing method are set on the trial bench first, so the output you compare is the output you get. If your grade is not in the tables, send it — the closest configuration is usually a change of screw set, not a different machine.

Related on this site: Machine range: KTE-50B to 135D · Pelletizing methods compared · quotation and free trial · Wikipedia: Masterbatch